Friday, January 14, 2022

What is the hybridisation of [Mn( CN) 6] 3-?

[Mn(CN)6] ^ 3- is made up of 6 CN- ions and Mn ^ 3 ion. The electronic setup of Mn ^ 3 ion is [Ar] 3d4. As CN- is a strong field ligand, 2 electrons are paired. 2 uninhabited 3d orbitals (dx2-y2 and d z2), one fours orbital and 3 4p orbitals are hybridized and results in d2sp3 hybridization. The shape of the complex is octahedral.
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